Assessment of Mineral Composition of Irrigated Water from Different Wells around Ta'if City, Saudi Arabia

AbSTrACT The chemical composition of water collected from different wells in Ta'if city was evaluated in order to determine the suitability as a potable or at least for irrigation. This study indicated that most of the chemical parameters such as. Ba, Cd, Cr, Zn & Fe do not fall within the permissible limit. Anions varied greatly between water sampled collected from different wells. Cl-varied between 32-955 mg L-1 ,which is higher than EPA standards (200 mg L-1). NO 3-2 ranged between 14.6-2088 mg L-1 , which is much higher that allowed levels by EPA (10 mg L-1). Similarly, NH 4 was relatively higher than standards of 10 mg L-1 in three wells out of the ten wells examined. Cations also showed similar trend, as they showed maximum in samples collected from some wells and lower concentrations and even BDL in samples collected from others. Na+ and Mg+ exceeded the standard levels (200 and 30mg L-1 respectively). K+ was lower than EPA standards of 30 mg L-1 in all samples Five metals out of the 10 elements analysed in the water samples from suburban water wells were found in concentrations exceeding various standards, which are Al, B, P , Cu and Pb However other trace metals (Fe, Ba, Cd, Cr and Zn) were not detected in all water samples

Access to adequate water for irrigation is a matter of increasing concern all over the globe especially in arid and semiarid areas 1 -4 .People are using sewage for irrigation of agricultural land due to scarcity of fresh and underground water.
The growing problem of water shortage has significant negative influence on economic development, human livelihoods, and improving the environment nature throughout the world 4 .To face the growing demand for irrigation water, non conventional resources are often used [4][5][6] .Clean potable water is a must for our daily life.Drinking water should be pure and free of contaminants to ensure health and wellness 6,7 .
There are three main types of water source in Saudi Arabia namely rain, surface and ground (well) water 8 .The later generally less expensive to develop for use, and usually provides a more certain supply.It is generally preferred as a source for municipal and industrial water supplies.Ground water is the most choice in areas where there is no surface water body However, it is often high in mineral contents and may be contaminated by hazardous or toxic materials leaking from landfills, waste treatment sites, or other sources 9 .
In areas with a shallow freshwater system, groundwater may easily be contaminated from onsite sewage treatment systems which are typically installed less than 1 m above the water table and may be flooded during heavy rains.The discharge of non point source pollution from these systems to shallow groundwater and ultimately to surface waters could be an important source of contamination for estuary environments 10 .
Despite a need to understand the groundwater quality status and its potential adverse environmental impacts upon the surface water quality, there are insufficient studies that have comprehensively summarized the quality status in this Saudi Arabia.The goals of this study were to characterize the nutrient dynamics in the major wells in Ta'if city to: (1) evaluate the groundwater nutrient contamination (2) determine the site variations of groundwater nutrients, and (3) determine the seasonal variations of groundwater nutrients.

Study location
Ta'if is located south east to Jeddah City (N 21° 15, E 40° 95) 17 meters above sea level.It's population around 1.5 million (Fig. 1).
Water samples were collected from 12 different wells around the city extended 10 km South East (indicated with a red arrow on Fig. 1).

Elemental analysis
Water samples were collected in 250 mL plastic containers from the ten wells along the transict in the city.The containers were tightly closed, placed in an ice box (5°C) and then transported to the laboratory where they were then filtered and refrigerated before metal analysis, as described earlier 6,11 .
I n d u c t i ve l y c o u p l e d p l a s m a m a s s spectrometry (ICP-MS) was applied to determine the concentration of 10 trace elements (P, Pb, B, Al, Zn, Cr, Cd, Ag, Ba, and Cu) 13

Statistical analysis
Analysis of variance (ANOVA) was applied to log-transformed data.Significant differences between means were tested by LSD (Stattgraphics Statistical Package, Plus 5.1, Informer Technologies, Inc., USA).

Fig. 1: Map of Ta'if showing locations and directions of sampling wells marked with red arrow rESuLTS AnD DISCuSSIon
Saudi Arabia faces numerous environmental challenges.The country has very little arable land.Water scarcity is a constant concern, as are the related issues of desertification and creeping sands.The region's dryness results in frequent dust and sand storms that can cripple transportation.The lack of water bodies poses a continual challenge, as does the depletion of underground water resources.
A n a l y t i c a l r e s u l t s s h o w t h a t t h e concentrations of nutrient constituents and the values of other related parameters varied from location to location as well as from season to season.Table 1 summarizes the mean concentrations of the selected nutrients Anions varied greatly between water sampled collected from different wells.Cl-varied between 955 mg L -1 in well 1 to 32 mg L--1 in well 5.It was higher the EPA standards (200 mg L -1 ) in water collected from wells 2 and 6.NO3-2 ranged between 2088 mg L -1 in well 2 to 14.6 mg L -1 in well 10, which is much higher that allowed levels by EPA (10 mg L -1 ).Similarly, NH4 in samples collected from well 2 was higher (10.86 mg L -1 ) than that collected from well 1 (0.38 mg L -1 ).SO4-2 was recorded in tow wells only (2 and 3 and) and there was no traces in other wells i.e. below detection limit (BDL) Table 1.SO4-2 was lower than the USEPA Standards of 250 mg L -1 and Saudi standards of 400 mg L -1 , while NH4 was relatively higher than standards of 10 mg L-1 in three wells out of the ten wells examined.*BDL= below detection limit Cations also showed similar trend, as they showed maximum in samples collected from some wells and lower concentrations and even BDL in samples collected from others.Na+ exceeded the standard levels (200 mg L -1 ) in well 2 (560 mg L -1 ), while others were around and even below the standard level.Similarly Mg+ exceeded the standards of 30 mg L -1 in wells 2, 3 and 6 (71, 35.8 and 34 mg L -1 , respectively).However, K+ was lower than EPA standards of 30 mg L -1 in all samples.
Concentrations of Al, B, P and Pb were exceeding permissible limits and International standards, while other trace metals (Fe, Ba, Cd, Cr and Zn) were not detected in all water samples.Al was detected in water collected from well 2 (0.3 mg L -1 ) and 3 (0.07 mg L -1 ) which is higher than EPA standard (0.05 mg L-1) (Table 1).While, Pb and B were detected in all water samples.Pb exceeded the standard level of 0 mg L -1 in all well.Moreover, B exceeded the EPA level (0.1 mg L -1 ) in many wells.Cu was much lower than EPA standards (1.3.mg L -1 ) in water collected from all wells, its concentration ranged between 0.068 to 0.083 mg L -1 .
Spatial distribution of water soluble inorganic ions and trace metals is shown in figures 2 and 3, respectively.
It is clear that Well 2 and 10 had the lowest concentrations of water soluble inorganic matter.While, wells 2 and 6 had the highest concentrations.
Moreover, Trace metals showed the same trend, as wells 1 and 10 had the lowest concentrations of heavy metals while wells 2 and 6 had the highest ones (Fig 3).Wells 2 and 6 were more close to heavy industry and traffic roads than others and this could be the reason why they are more contaminated with trace metals and water soluble inorganic ions and this in agreement with the general view in the literature.
Trace metals can cause change in cloth colors and even color removal of, moreover they can remove colors household appliances if present in high concentrations 13 .Using water having high concentrations of Cu and Al exceeding the acceptable levels for irrigation can potentially have a toxic effect on plants .EPA standards for Boron were exceeded in the present study and these concentrations are known to cause irritation of skin upon contact.Moreover, Pb was found at concentrations that would pose risk for public health.It could come from flashing on the roofs 14 .
The source of trace metals could be corrosion of household plumbing systems; erosion of natural DEPOSITS , while anions and cations could be due to runoff from fertilizer use; leaking from sewage and/or erosion of natural deposits 14,15 .
It is well known that presence of to traffic or to industrial activities in close proximity to water bodies is main sources elevated contaminants in water.However, these were not found to be important explanatory variables for Fe, Ba, Cd, Cr and Zn in this study.Therefore, there was insufficiently reliable information collected to allow us to draw any firm conclusions 14 .Future research is planned to attempt to identify the sources of trace metals.
This study indicated that most of the chemical parameters such as do not fall within the permissible limit.Therefore, currently the related government departments should focus on regular monitoring of groundwater quality.
In conclusion, the use of this water could pose a health and/or an environmental risk, especially in regards to the high concentrations of trace metals such as Pb, Al and Cu.These risks need to be addressed if wells are to provide an alternative water source for cities in Saudi Arabia.
The qualities of the well water samples were therefore not suitable for human consumption without adequate treatment.Moreover, regular monitoring of groundwater quality, abolishment of unhealthy waste disposal practices and introduction of modern techniques are recommended.
Creating awareness in society about presence of iron in groundwater and its adverse effects should be carried out by municipal corporation authorities and alternative safe irrigation water should be made available to individuals from study area.The presence of trace metals and inorganic ions in groundwater in study area which has prominently socially and economically weaker individuals and thus they may be not in a position to afford expensive water filtration devices, hence, an alternative low cost technology based on adsorption or absorption needs to be developed for removal of these contaminants in groundwater which can be easily adopted by these local inhabitants 11,15 .

Fig. 2 :Fig. 3 :
Fig. 2: Variations in anions and cations between different wells (Each figure is a mean of 3 replicates + 1 SE)

Table 1 : Mean elemental concentrations (mg L-1) of water collected from different wells in Ta'if City. ba, Cd, Cr, Zn & Fe (bDL) in all samples
*BDL = below detection limit