An Evaluation of Water Quality from Siahrod River , Haraz River and Babolrood River by NSFWQI index

In many countries such as Iran, social and industrial developments changed the qualitative characteristics of the river‘s water quality and leads to excessive pollution. The first step for river water quality management is obtaining information on changes of river water quality in dimensions of time and place and also, determination of major sources of pollutants. WQI is a mathematical and statistical tool for conversion of quantitative values of large quantity of water quality data into single number which presents a simple and understandable tool for qualitative assessment. In current study, samples were collected from stations at up, middle and downstream of three rivers in Mazandaran province (Siahrod River, Haraz River and Babolrod River) in a 2 years interval of 2012-2013 years. The values of NSFWQI (water quality index of America’s national health organization) were calculated for all stations and all of the stations were located on the level of unsuitable conditions. According to NSFWQI, the best condition was related to the upstream of Haraz River and the worst condition was related to the downstream of Siahrood River.


INTRODUCTION
The increased use of water resources, unnatural manipulation and changes in river water quality have been increased.In all around the world, human activities have profound effects on rivers and lakes.Rivers are exposed to large amounts of household wastewater, industrial swages, agricultural swages, mine wastes, urban wastewater, radioactive materials, pesticides and numerous other contaminants (Wongsupapa, C., et al., 2009) The first step for keeping river water quality and purification of polluted parts is obtaining information on the qualitative changes of river water in dimensions of time and place and also, determination of major sources and various water pollutants (Oguchi, T., 2009, SahaP., 2010).Analysis of measured parameters alone or in combination, give incomplete information on water quality because of variety of parameters, samples and stations.Mathematical-computer qualitative modeling of river water also needs broad hydrodynamic and hydrological information (Silva f., et al., 2000, Ormsbee, L., 2006).Water quality index (WQI) is developed to solve this problem.WQI is first represented by Brown in 1970.
WQI is a mathematical and statistical tool for conversion of quantitative values of large quantity of water quality data into a single number.It provides a simple and understandable tool for managers and policy makers to obtain information on water quality and decide to allow the permitted uses of water.Also, application of WQI specifies the process of variations and qualitative trends of water resources (Brian O., 2005) and also allows the classification of water quality.Published indicators have various types that developed according to specific methods of each region and available standard in it, such as NSFWQI, OWQI and etc.Among the various indexes which are applicable for water quality zoning, NSFWQI was selected because of high precision, simplicity and availability of the required parameters (Shamsai et al., 2006).
According to previous studies, Mirmoshtaghi in 2011, studied the water quality of Sefidrood River by investigation of 20 samples at 5 sampling stations according to NSFWQI index and compared the results with OWQI index.The results showed that maximum and minimum values of NSF were 57 and 32, respectively.And the average value of NSFWQI along with Sefidrood River was obtained equals to 47.5, which is placed at bad region.Also, calculation of OWQI index showed the very bad quality of Sefidrood River during the study period (Mirmoshtaghi, 2012).
In this study, classification of three river's water quality in Mazandaran province is investigated by NSFWQI index.

NFSWQI
After measuring of 9 above mentioned factors, each sub-index is obtained according to the conversion curves (appendix).The following equation ( 1) is applied for calculation of final index.

NSFWQI = €
Where, "n" is the number of sub-index, "k" is weighting factor and "I" is sub-index obtained from conversion curves according to Table 1.

To determine the NSFWQI index, 9 parameters are measured for reasons as described below: Biological oxygen demand (BOD)
BOD test gives an approximate estimation of the amount of biodegradable waste materials in the water.Biodegradable waste materials are usually consists of organic waste such as leaves, grass and fertilizers.

Dissolved Oxygen (DO)
DO test specify the amount of required dissolved oxygen for continuity of life in water.This oxygen is available for fishes, invertebrates and all animals living in the water.Decrease of dissolved oxygen is a sign of probable pollution in water (Abraham W.R., 2011, Yau, J., 2003).

Fecal coliform
Fecal coliform is a bacterium available in human and animal waste.

Nitrate
Nitrate is one of the major pollutantsin water.Nitrates are harmful for human because oxidize into nitrite and affects on the ability of red blood cells that carry oxygen.Nitrites also cause very acute disease in fish.

pH
Most of aquatic organisms are very sensitive against the pH.Appropriate pH for survival in river is usually from 6.5 to 8.5 (Nwajei, G., et

Total dissolved solids (TDS)
TDS is dissolved materials in river water includes salts, some of organic materials and wide range of nutrients, toxic materials and etc. Very high or low concentration of dissolved materials affects on the growth and lead to death of aquatic life (Parihar, S., et al., 2012;Murhekar H., et al., 2012)

Total phosphate
Phosphate is essential for the growth of animals and plants.total phosphate shows the available values of phosphate in aquatic resources.

Turbidity
Turbidity is calculated by using light scattering in water column due to suspended solids.High turbidity will cause more water darkness (Muthusamy P., et al. 2012).If water became very dull, its ability in maintaining most of plants and microorganisms will be removed.NSFWQI index is a reduction index namely it is decreases with increasing of water pollution.This index has a value between 0 to 100 and is classified according to

Sampling method and analysis of factors
Samples were collected seasonally from stations at upstream, middle stream and downstream of rivers (Siahrod River, Haraz River and Babolrod River) in a 2 years interval of 2012-

RESULTS
The obtained results in a 2 years of 2012-2013 from stations of upstream, middle stream and downstream is calculated and measured and are as follows (Table 3):  The obtained values of NSFWQI at stations are as follows, which shows that the water quality at all stations are unsuitable according to Table 4 and Figure 2.
Figure 2 shows that downstream of Babolrood River had a much worse situation than other rivers, due to discharge of numerous factories swages in to the river.Babolrood River condition was relatively more appropriate than Siahrood River due to placement of upstream at a more pristine region relative to other up streams and less villages and residential cities around the river.
Selection of monitoring stations in Department of Environmental Protection was so that upstream stations were determined at appropriate distance before the entrance of cities, middle stream at city center and downstream near the sea entrance.Figure 3 shows that DO in all rivers are decreased because of industrial and agricultural drainage.It also shows thatself-purification capacity of the rivers is not enough for purifying of the rivers.

CONCLUSION
According to the obtained results, it is required that each river be investigated more closely as case study and with selection of more stations to specify the sources of pollutants.And by investigation of other available indexes and matching them with hydrological and climatic conditions of Mazandaran's Rivers, design the convenient and reliable index.
The obtained results showed that qualitative condition of Mazandaran's Rivers is unsuitable and appropriate management measures such as population load and excess urban activity in the basin of this river, industrial activities, excessive consumption of chemical fertilizers and pesticides, discharge of rural, urban and industrial wastewater and also solid wastes into the river which have a continuous increasing trend are the main source of river pollution.
So, human factor is the main cause of river pollution.Besides human factors, natural factors such as low rainfall, water consumption for agricultural and industrial purposes, development of agricultural lands at the expense of natural lands wastefulness and finally, all increased the physical and chemical pollution of the river and leads to natural disruption of its biological and bioavailability capacity.
The values of NSFWQI (water quality index of America's national health organization) were calculated for all stations and all of the stations were located on the level of unsuitable conditions.According to NSFWQI, the best condition was related to the upstream of Haraz River and the worst condition was related to the downstream of Siahrood River.